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Thermophysical study of neutron irradiated silicon nitride nanoparticles/ Naghiyev, Tural G.

Məqalədə neytron şüalanmasının Si₃N₄ nanohissəciklərinin istilik-fiziki xassələrinə təsiri araşdırılmışdır. Bunun üçün 300–1400 K temperatur intervalında diferensial termik analiz aparılmış, entalpiya, entropiya və Gibbs sərbəst enerjisi qiymətləndirilmişdir.

 Thermophysical study of neutron irradiated silicon nitride nanoparticles/ Naghiyev, Tural G.

Abstract

Silicon nitride (Si3N4) nanoparticles were irradiated with neutrons at different energy fluxes. Differential thermal analysis of non-irradiated and neutron irradiated samples was performed in the temperature range of 300-1400 K. Based on the obtained experimental results, relevant thermophysical parameters were calculated and discussed in detail. All analyses were comparatively discussed for non-irradiated and neutron irradiated nano-Si3N4 particles. On the basis of endotherms observed in DTA spectra, entropy and enthalpy in Si3N4 are interpreted in detail. Compared with the non-irradiated sample, slightly negative values of enthalpy indicate the formed 31P isotope due to neutron irradiation. In the mentioned temperature range, the values of the free Gibbs energy were calculated for all samples, and it was determined that it is varied around zero up to 600 K. Moreover, the effect of neutron transmutations on heat transfer in Si3N4 nano particles has been studied.

https://www.scopus.com/pages/publications/85150718522?origin=resultslist